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Back to tab navigation Download options Please wait The article was received on 26 Apraccepted on 20 Sep and first published on 21 Sep The catalysts show similar catalytic efficiency as the homogeneous catalyst in the model cyclopropanation between ethyl diazoacetate EDA and styrene.

For reproduction of material from all other RSC journals and books: For reproduction ghtmann material from NJC: Previous Article Next Article. Catalytically active dirhodium sheet-like coordination polymers are synthesized from their precursors via ligand exchange. Supplementary information PDF K. baga

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DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process. Information about reproducing material from RSC articles with different gutmajn is available on our Permission Requests page. XX is the XXth reference in the list of references.


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Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in gjtmann — a structural study.

Publications – Nachwuchsgruppe Gutmann – Technische Universität Darmstadt

Aany Sofia Lilly Thankamony. Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J.

Back to tab navigation Fetching data from CrossRef. Jump to main content. The individual lamellae of the dirhodium-bdc frameworks are stacked as parallel sheets, which are randomly oriented or slightly ordered.


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Residual trifluoroacetate species are investigated by quantitative 19 F MAS NMR which further reflects the configuration of trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure. If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc. If you are the author of this article you still need to obtain permission to reproduce the whole article in a third gutmwnn publication with the exception of reproduction of the whole article in a thesis or dissertation.

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Fetching data from CrossRef. The stability and reusability of the catalysts are verified by TG-DTA measurements tutmann leaching tests. Jump to site search. Reproduced material should be attributed as follows: